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Oxidation of substituted phenols with the ClO2—VO(acac)2 system

  • I. V. Loginova,
  • I. Yu. Chukicheva,
  • I. V. Fedorova,
  • A. V. Kuchin

摘要

The oxidation of a series of alkylphenols (alkyl is methyl and/or isobornyl) with chlorine dioxide using the VO(acac)2 as the catalyst was studied. In the presence of VO(acac)2, the selectivity to quinones increases and the yield of oxidative chlorination products decreases significantly.