Analysis of the intermediates of the catalytic system for the Chan—Evans—Lam reaction based on Cu(i) complex with N-heterocyclic carbene
摘要
The complex dynamic nature of the Chan—Evans—Lam catalytic system in the presence of CuCl complex with N-heterocyclic carbene (1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene) was demonstrated. The appearance of metal nanoparticles in this system was theoretically and experimentally substantiated.