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Influence of the structure of benzylaminate C,N-palladacycles on their catalytic activity in the Suzuki—Miyaura reaction

  • O. N. Gorunova,
  • M. P. Timerkaeva,
  • K. A. Kochetkov,
  • V. V. Dunina

摘要

Benzylaminate C,N-palladacycles exhibit high catalytic activity in the Suzuki—Miyaura cross–coupling of p-bromoanisole with phenylboronic acid under mild conditions. The influence of the α-substituent and the environment of the nitrogen atom in azapalladacycles on their efficiency as catalysts was assessed.