<p>In this context, we introduced the immobilization of CuI nanoparticles on to the surface of 2,2′-bipyridine functionalized magnetic nanoparticles to create a heterogeneous catalytic system [Fe<sub>3</sub>O<sub>4</sub>@SiO<sub>2</sub>@2,2′-BP@CuI NPs]. After characterization of prepared hybrid structure by using suitable methods such as Fourier-transform infrared spectroscopy (FTIR), thermogravimetric/derivative thermogravimetry (TG/DTG), X-ray diffraction (XRD), energy-dispersive X-ray spectroscopy (EDS), field-emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), and vibrating-sample magnetometer (VSM), its catalytic behavior for the preparation of 1,2,3‐triazoles derivatives has been analyzed. Also, recovering and reusing behavior of Fe<sub>3</sub>O<sub>4</sub>@SiO<sub>2</sub>@2,2′-BP@CuI NPs show promising results of four runs while only a slight decrease in the performance of the catalyst was observed.</p>

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CuI nanoparticles immobilized on Fe3O4@SiO2@2,2′-bipyridine: an efficient catalyst for 1,2,3‐triazoles synthesis

  • Abolfazl Heydari,
  • Meysam Yarie,
  • Morteza Torabi

摘要

In this context, we introduced the immobilization of CuI nanoparticles on to the surface of 2,2′-bipyridine functionalized magnetic nanoparticles to create a heterogeneous catalytic system [Fe3O4@SiO2@2,2′-BP@CuI NPs]. After characterization of prepared hybrid structure by using suitable methods such as Fourier-transform infrared spectroscopy (FTIR), thermogravimetric/derivative thermogravimetry (TG/DTG), X-ray diffraction (XRD), energy-dispersive X-ray spectroscopy (EDS), field-emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), and vibrating-sample magnetometer (VSM), its catalytic behavior for the preparation of 1,2,3‐triazoles derivatives has been analyzed. Also, recovering and reusing behavior of Fe3O4@SiO2@2,2′-BP@CuI NPs show promising results of four runs while only a slight decrease in the performance of the catalyst was observed.