Scholarlink

<p>In synthetic chemistry, cycloaddition is a valuable tool for creating heterocyclic rings, with numerous applications in a variety of fields. The objective of this research is to develop a NiCu/ZIF-8 catalyst to facilitate a three-component reaction known as the "click reaction," which is used to synthesize 1,2,3-triazoles. The catalyst was designed to catalyze 1,3-dipolar cycloaddition reactions involving several azides and alkynes. The metals nickel and copper were immobilized on the surface of ZIF-8 to maximize the catalyst's performance. The catalyst was characterized using various analytical methods, including scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), and energy-dispersive X-ray spectroscopy (EDX). Remarkably, the catalyst demonstrated stability, maintaining its catalytic properties and efficiency after five recycling cycles. The advantages of this procedure are manifold, including high speed, mild conditions, reusability, high yield (75–95%), and affordability, which make it an attractive method for 1,3-dipolar cycloaddition reactions.</p>

错误：搜索内容不能为空，请输入英文关键词
错误：关键词超出字数限制，请精简
高级检索

Unveiling the synergistic interplay between Cu and Ni with ZIF-8 nanomaterials: a catalyst for the synthesis of triazole derivatives in nanoscale chemistry

  • 期刊论文

  • 发表日期：

    2025年2月4日

查看全文
  • Pouya Taheri,
  • Pegah Molaei,
  • Atieh Abazari,
  • Mahmood Tajbakhsh,
  • Elham Yeganeh-Salman,
  • Moein ghorbanian

摘要

In synthetic chemistry, cycloaddition is a valuable tool for creating heterocyclic rings, with numerous applications in a variety of fields. The objective of this research is to develop a NiCu/ZIF-8 catalyst to facilitate a three-component reaction known as the "click reaction," which is used to synthesize 1,2,3-triazoles. The catalyst was designed to catalyze 1,3-dipolar cycloaddition reactions involving several azides and alkynes. The metals nickel and copper were immobilized on the surface of ZIF-8 to maximize the catalyst's performance. The catalyst was characterized using various analytical methods, including scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), and energy-dispersive X-ray spectroscopy (EDX). Remarkably, the catalyst demonstrated stability, maintaining its catalytic properties and efficiency after five recycling cycles. The advantages of this procedure are manifold, including high speed, mild conditions, reusability, high yield (75–95%), and affordability, which make it an attractive method for 1,3-dipolar cycloaddition reactions.