We use nearly parallel pure states to characterize positive linear functionals \(\phi \) on \(\mathbb {M}_n\) as positive multiples of the trace if and only if \(\phi (A \natural B) \le \sqrt{\phi (A) \phi (B)}\) for all positive definite matrices A and B. Here \(A \natural B = (A^{-1} \# B)^{1/2} A (A^{-1} \# B)^{1/2}\) represents the spectral geometric mean. For further clarification, we establish novel characterizations through the inequality \(\phi (A \natural B) \le \phi ((A+B)/2)\) for all positive definite matrices A and B. We also present a trace inequality related to quantum fidelity that applies to all positive definite matrices, and demonstrate that it does not characterize the trace.