Characterization of δ-PuGa (1 at%. Ga) Oxidation Under Dry Oxygen Atmosphere Exposure

The oxidation of δ-stabilized plutonium alloy was studied under dry oxygen exposures for temperatures varying from 100 up to 300 °C and oxygen partial pressures varying from 10^–4 up to 500 mbar. The coupling of X-ray diffraction, Raman spectroscopy and FIB-SEM has allowed to show that the oxide scale is composed of an outer layer of PuO₂ and an inner mixed layer of α + β-Pu₂O₃ platelets propagating into a metallic zone corresponding to the stable phase of unalloyed Pu. Furthermore, the analysis of Pu oxidation kinetics has displayed first a parabolic growth governed by the diffusion of interstitial oxygen. This step consists of the thickening of the Pu₂O₃ layer with a decrease in α-Pu₂O₃ ratio in favor of β-Pu₂O₃. Then, a second step occurs consisting of a linear growth of the PuO₂-layer with the formation of thick nodules which tend to cover the whole oxide surface. Based on the results of this work, a general oxidation mechanism for δ-Pu alloy is provided.