<p>An exclusive set of Dy³⁺ ions doped AgNO₃-incited Borotelluro-phosphate glass samples with the configuration (29.5−<i>x</i>)B₂O₃+<i>x</i>AgNO₃+20TeO₂+20BaO+20BaF₂+10P₂O₅+0.5Dy₂O₃ (<i>x</i>= 0 0.05, 0.075, 0.1, 0.5 and 0.75 in wt.%) were fabricated by the traditional melt-quenching approach. The structural behavior has been confirmed via the XRD profile, which exhibits an amorphous nature. The bending and stretching vibration of the host matrix was affirmed through FTIR spectral studies. The physical attributes of the synthesised samples were estimated, and the BTPBBDy: 0.75Ag glass sample has a higher density (3.811 g/cm³), higher refractive index (1.737) and a higher concentration of rare earth ions (1.698×0²⁰&#xa0;ions/cm³), which reveals a more compact structure within the glass network among the other samples. From the optical absorption spectral analysis, the bonding parameters, oscillator strengths and JO intensity parameters of the fabricated glass samples were estimated and reported. For all the equipped samples, JO parameters exhibit the trend as Ω₂&gt;Ω₄&gt;Ω₆. These results demonstrate that the BTPBBDy:<i>x</i>Ag glasses reveal a higher asymmetry around the Dy³⁺ ions. From the emission spectra, three spectral transitions ⁴F_9/2→⁶H_11/2 (red), ⁴F_9/2→⁶H_13/2 (yellow), ⁴F_9/2→⁶H_15/2 (blue) were observed at the wavelengths of 664, 576 and 484 nm respectively. The radiative properties, lifetime and efficiency were estimated through emission, JO parameters and decay analysis. For all the glasses, decay from the ⁴F_9/2 excited state is obtained to be non-exponential in nature. The color chromaticity coordinates are estimated and plotted in the 2D-color CIE diagram; all the samples exhibit emission in the bluish white region.</p>