<p>Mercury (Hg<sup>2+</sup>) and lead (Pb<sup>2+</sup>) are among the most hazardous heavy metals, so effective monitoring systems for their detection in water are needed to protect environment and public health. This study numerically explores a dual-channel surface plasmon resonance (SPR) sensor based on a uniform-waist tapered optical fiber, designed to detect Hg<sup>2+</sup> and Pb<sup>2+</sup> simultaneously. Sensing channels are engineered with different thin-film metal coatings and optimized taper ratios. One channel incorporates MoS<sub>2</sub> over a silver film, while the other used graphene over gold, both utilizing the strong adsorption capability of 2D materials. The sensor’s performance is evaluated across a sensing medium refractive index (SMRI) range of 1.333–1.342. After structural optimization, the sensor is evaluated for the simultaneous detection of Hg<sup>2+</sup> and Pb<sup>2+</sup> ions within concentration range of 70 to 1000 ppm. The sensor achieved a maximum sensitivity of 0.0242&#xa0;nm/ppm for Hg<sup>2+</sup> with a corresponding detection limit of 21.56 ppm, while the recorded sensitivity and detection limit for Pb<sup>2+</sup> were 0.0251&#xa0;nm/ppm and 19.17 ppm, respectively. The proposed dual-channel tapered SPR configuration presents a compact, cost-effective, and highly sensitive platform for the detection of heavy metals.</p>

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Design of a dual-channel fiber optic SPR sensor for the simultaneous measurement of Hg2+ and Pb2+ ions

  • Vikas,
  • Paola Saccomandi

摘要

Mercury (Hg2+) and lead (Pb2+) are among the most hazardous heavy metals, so effective monitoring systems for their detection in water are needed to protect environment and public health. This study numerically explores a dual-channel surface plasmon resonance (SPR) sensor based on a uniform-waist tapered optical fiber, designed to detect Hg2+ and Pb2+ simultaneously. Sensing channels are engineered with different thin-film metal coatings and optimized taper ratios. One channel incorporates MoS2 over a silver film, while the other used graphene over gold, both utilizing the strong adsorption capability of 2D materials. The sensor’s performance is evaluated across a sensing medium refractive index (SMRI) range of 1.333–1.342. After structural optimization, the sensor is evaluated for the simultaneous detection of Hg2+ and Pb2+ ions within concentration range of 70 to 1000 ppm. The sensor achieved a maximum sensitivity of 0.0242 nm/ppm for Hg2+ with a corresponding detection limit of 21.56 ppm, while the recorded sensitivity and detection limit for Pb2+ were 0.0251 nm/ppm and 19.17 ppm, respectively. The proposed dual-channel tapered SPR configuration presents a compact, cost-effective, and highly sensitive platform for the detection of heavy metals.