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Synthesis of Azo-BE: nonlinear optical properties studies at visible, cw, laser beams

  • Uhood J. Al-Hamdani,
  • Qusay M. A. Hassan,
  • Ayat K. Hashim,
  • H. A. Sultan,
  • T. A. Alsalim,
  • C. A. Emshary

摘要

4-((6-Methylbenzo[d]thiazol-2-yl)diazenyl)phenyl 4-chlorobenzoate(Azo-BE) is synthesized and characterized using 1HNMR and 13CNMR, mass spectra, differential scanning calorimetry, optimized structure and calculation of HOMO (H) and LUMO (L) and gap energy. The Azo-BE nonlinear optical properties using cw laser beam of wavelength 473 nm are studied. The nonlinear refraction index, n2, of Azo-BE is calculated using the same wavelength via the diffraction patterns and Z-scan. n2 value of 3.121 × 10–11 m2/W is obtained. It appears that Azo-BE bare no nonlinear absorption coefficient, β, at 473 nm beam and power input used. All optical switching, static and dynamic, are tested in Azo-BE using 473 and 532 nm laser beams.