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<p>The ring-opening polymerization lays the foundation for synthesizing polypropylene glycol. Nevertheless, homogeneous alkali catalysts usually require complex post-treatments, hindering green synthesis and environmental sustainability. Here, we studied a heterogeneous epoxide polymerization method based on a P123-modified nanocomposite layered double oxide (CoMgAl-LDO(P123)). Thereafter, the composition, crystal structure, morphology, and thermal stability of the catalyst were characterized through SEM, XRD, FTIR, XPS, BET, and TG-DTG techniques. The results indicated that due to the designable and self-assembled P123 micelles, CoMgAl-LDO(P123) generated consistent mesoporous channels and a larger specific surface area. The introduction of cobalt enriched the alkaline sites on the CoMgAl-LDO(P123) surface. In the synthesis of small molecular weight poly(propylene glycol) (i.e., number average molecular weight less than 500), the catalytic performance of CoMgAl-LDO(P123) for the conversion of propylene oxide reached 96.3% under the optimal reaction conditions, which was superior to that of other catalysts. Our strategy addresses the trade-off issue that alkali catalysts faced in terms of sustainability and operational complexity, holding great promise in green chemistry.</p>

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P123-CoMgAl composite for sustainable and high-conversion epoxide ring-opening polymerization

  • 期刊论文

  • 发表日期：

    2025年5月1日

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  • Xiaoyan Cao,
  • Xiao Xu,
  • Gongming Wu,
  • Zhenggui Gu

摘要

The ring-opening polymerization lays the foundation for synthesizing polypropylene glycol. Nevertheless, homogeneous alkali catalysts usually require complex post-treatments, hindering green synthesis and environmental sustainability. Here, we studied a heterogeneous epoxide polymerization method based on a P123-modified nanocomposite layered double oxide (CoMgAl-LDO(P123)). Thereafter, the composition, crystal structure, morphology, and thermal stability of the catalyst were characterized through SEM, XRD, FTIR, XPS, BET, and TG-DTG techniques. The results indicated that due to the designable and self-assembled P123 micelles, CoMgAl-LDO(P123) generated consistent mesoporous channels and a larger specific surface area. The introduction of cobalt enriched the alkaline sites on the CoMgAl-LDO(P123) surface. In the synthesis of small molecular weight poly(propylene glycol) (i.e., number average molecular weight less than 500), the catalytic performance of CoMgAl-LDO(P123) for the conversion of propylene oxide reached 96.3% under the optimal reaction conditions, which was superior to that of other catalysts. Our strategy addresses the trade-off issue that alkali catalysts faced in terms of sustainability and operational complexity, holding great promise in green chemistry.