Investigation of pure TiO2 and BaO-loaded TiO2 nanocomposites with enhanced photocatalytic activities
摘要
In this study, pure TiO2 and 5 wt% BaTiO3 nanocomposites were synthesized using the sol–gel method. The crystal structure, morphology, optical properties, and chemical composition of the synthesized nanoparticles were characterized by using XRD, SEM, HR-TEM, UV–vis spectroscopy, and XPS. The average crystallite sizes of the pure TiO2 and 5 wt% BaTiO3 were approximately 15.2 nm and 8 nm, respectively. Particle size is affected by the nature of the surfactant. Spherically shaped nanoparticles with aggregation and a homogeneous size distribution were observed using SEM and HR-TEM. The bandgap was determined to be 3.24 eV and was found to have excellent optical behavior. The chemical and electronic states of the BaTiO3 nanoparticles were determined by XPS. The nanoparticles photocatalytically degraded the Congo red dye in an aqueous solution. Compared to pure TiO2 nanoparticles, 5 wt% BaTiO3 nanoparticles with surfactant assistance demonstrated better photocatalytic activity.