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Detectable and facile electrodeposited nanoscale homogenous distribution of AgCl deposits in Ag thin films

  • S. Grewal,
  • C. Leverant,
  • L. C. Merrill,
  • K. Klavetter,
  • M. P. Siegal

摘要

Pulsed electrodeposition of Cl ions, together with pre-oxide removal treatments, can achieve uniform nanoscale AgCl deposits (< 2 to 20 nm within an Ag thin film while edge-effect barriers (masking) evenly distribute electric fields for microscale areal homogeneity. The AgCl uniformity was analyzed using materials characterization techniques (electron and X-ray fluorescence imaging) and electrochemical detection (cathodic stripping voltammetry).