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Photocatalytic C-H activation for C-N/C-S bond formation over highly efficient solar light active supramolecular network organogels

  • Geeta Srivastava,
  • Rajesh Kumar Yadav,
  • Rehana Shahin,
  • Shaifali Mishra,
  • Aditya Nath Yadav,
  • Siddharth Singh Yadav,
  • Indra Kumari,
  • Kamani Singh,
  • Jin Ook Baeg,
  • Navneet Kumar Gupta

摘要

Although using solar energy for pharmaceutical manufacture presents hurdles, the potential benefits in terms of sustainability, cost-effectiveness, and technical innovation make it an exciting path for the scientific community to investigate and develop further. We present a highly efficient solar light active supramolecular network organogels as a photocatalyst. The as-prepared PVA@RhB and PVA@RhB@OG organogels as a photocatalyst catalytic materials were used to create C-N and C-S bonds for drug intermediates and value-added products because of their high bond energy, low polarity, and strong inertia C-H bond activation. The current research work sets a new standard for the environmentally friendly, highly selective C-H activation for the production of C-N/C-S bonds under solar light.

Graphical Abstract