Scholarlink

<p>This study explores the extraction potential of PCP, its ester derivative (PCP1), and its acid derivative (PCP2) towards uranium-238 from aqueous solutions. Preliminary tests revealed that PCP2 exhibits the highest extraction efficiency. Doehlert experimental design was applied to optimize solution pH and ligand mass. Optimal conditions were identified as pH 2.65 and 86.45 mg of PCP2, yielding extraction efficiency up to 85.93% from 2 mM uranyl acetate solution. Equilibrium uptake behavior was evaluated using adsorption isotherm models, while FTIR and TOF–SIMS analyses supported uranium uptake by PCP2. These results highlight PCP2 as a promising platform for uranium extraction studies.</p>

错误：搜索内容不能为空，请输入英文关键词
错误：关键词超出字数限制，请精简
高级检索

Extraction of 238U from aqueous solutions using functionalized phenoxycalix[4]pyrrole: complexation efficiency and optimum conditions

  • 期刊论文

  • 发表日期：

    2026年3月25日

查看全文
  • Sara Karnib,
  • Rana Baydoun,
  • Omar El Samad,
  • Wissam Zaidan,
  • Radwan Sidaoui,
  • Pierre-Edouard Danjou,
  • Francine Cazier-Dennin,
  • Bilal Nsouli

摘要

This study explores the extraction potential of PCP, its ester derivative (PCP1), and its acid derivative (PCP2) towards uranium-238 from aqueous solutions. Preliminary tests revealed that PCP2 exhibits the highest extraction efficiency. Doehlert experimental design was applied to optimize solution pH and ligand mass. Optimal conditions were identified as pH 2.65 and 86.45 mg of PCP2, yielding extraction efficiency up to 85.93% from 2 mM uranyl acetate solution. Equilibrium uptake behavior was evaluated using adsorption isotherm models, while FTIR and TOF–SIMS analyses supported uranium uptake by PCP2. These results highlight PCP2 as a promising platform for uranium extraction studies.