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Analyzing porosity of compacted bentonite via through diffusion method

  • Zhengye Feng,
  • Junlei Tian,
  • Xiaoqiong Shi,
  • Chao Wang,
  • Tao Wu

摘要

The diffusion behavior of ReO4 (as a surrogate for 99TcO4) and HSeO3 (as a surrogate for 79HSeO3) in compacted Wyoming bentonite was investigated. A through-diffusion experiment was conducted to measure the effective diffusion coefficient and the accessible porosity at high salinity. Two multi-porosity models (MP1 and MP2) were employed to analyze the effect of compaction on the accessible porosity, the diffuse double-layer porosity, and the interlayer porosity. The diffuse double-layer porosity increased with increasing the external surface area.