Valorization of hardwood sawdust as a reinforcing filler in Melt-Extruded Poly (Lactic acid) based composites using silly putty as a plasticizing additive
摘要
The timber industry yields substantial amount of sawdust which acts as a source of pollution without proper management. One of the possible applications of the waste material is in using it as a reinforcing filler in biopolymer composites and thereby fostering the circular economy. However, the brittle nature of such material creates hinderance in its mass production and prevents its widespread commercial use. To address the shortcoming, this study explored the novel application of silly putty as a plasticizing additive in polylactic acid (PLA)-sawdust based composites. The addition of 5 wt% silly putty to PLA significantly increased the blend and the composite’s elongation at break by up to 280% and 100% respectively in comparison to PLA. Compared to the PLA/sawdust composite, PLA/silly putty/sawdust composite exhibited fewer voids and irregularities on the fracture surface. The surface roughness for the PLA/silly putty/sawdust composite reduced to 36.8 nm compared to 185.8 nm for PLA/sawdust composite. The improved surface finish of an extruded material is critical for its functionality and aesthetics. The water contact-angle of the novel composite increased to 76.5° from 68.4° of native PLA/sawdust composite. Biocompatibility assays revealed that the developed product is not cytotoxic and, therefore, it is not expected to be hazardous upon exposure.