We present two limit theorems, a mean ergodic and a central limit theorem, for a specific class of one-dimensional diffusion processes that depend on a small-scale parameter \(\varepsilon \) and converge weakly to a homogenized diffusion process in the limit \(\varepsilon \rightarrow 0\) . In these results, we allow for the time horizon to blow up such that \(T_\varepsilon \rightarrow \infty \) as \(\varepsilon \rightarrow 0\) . The novelty of the results arises from the circumstance that many quantities are unbounded for \(\varepsilon \rightarrow 0\) , so that formerly established theory is not directly applicable here and a careful investigation of all relevant \(\varepsilon \) -dependent terms is required. As a mathematical application, we then use these limit theorems to prove asymptotic properties of a minimum distance estimator for parameters in a homogenized diffusion equation.