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<p>A strategy for determining consensus solubilities with measurement uncertainties at common temperatures from data reported at varying temperatures is presented. The approach involves fitting the individual data sets to an appropriate equation of solubility (or log solubility) as a function of temperature. This allows estimation of the standard uncertainty of each data point and, if required, interpolated values of the solubility, with uncertainties, at the temperatures of interest. Between-laboratory uncertainty is assessed by the DerSimonian–Laird procedure. The strategy is applicable to any measured quantity where its variation with experimental variables can be represented by a robust equation.</p>

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Strategy for Obtaining Consensus Solubility Values with Measurement Uncertainties at Given Temperatures from Published Data

  • 期刊论文

  • 出版模式：

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  • 发表日期：

    2025年10月16日

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  • W. Earle Waghorne,
  • D. Brynn Hibbert

摘要

A strategy for determining consensus solubilities with measurement uncertainties at common temperatures from data reported at varying temperatures is presented. The approach involves fitting the individual data sets to an appropriate equation of solubility (or log solubility) as a function of temperature. This allows estimation of the standard uncertainty of each data point and, if required, interpolated values of the solubility, with uncertainties, at the temperatures of interest. Between-laboratory uncertainty is assessed by the DerSimonian–Laird procedure. The strategy is applicable to any measured quantity where its variation with experimental variables can be represented by a robust equation.