<p>This manuscript investigates the magnetocaloric effect and magnetic properties of the Gd<InlineEquation ID="IEq3"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="10948_2025_6970_Article_IEq3.gif" Format="GIF" Height="10" Rendition="HTML" Resolution="72" Type="Linedraw" Width="8" /> </InlineMediaObject> <EquationSource Format="TEX">\(_3\)</EquationSource> <EquationSource Format="MATHML"><math> <mmultiscripts> <mrow /> <mn>3</mn> <mrow /> </mmultiscripts> </math></EquationSource> </InlineEquation>In compound as functions of magnetic field and temperature using a mean-field approximation. We first introduce the model and methodology, followed by the determination of the transition temperature through the analysis of magnetization, susceptibility, and magnetic entropy change (<InlineEquation ID="IEq4"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="10948_2025_6970_Article_IEq4.gif" Format="GIF" Height="16" Rendition="HTML" Resolution="72" Type="Linedraw" Width="51" /> </InlineMediaObject> <EquationSource Format="TEX">\(-\Delta S_m\)</EquationSource> <EquationSource Format="MATHML"><math> <mrow> <mo>-</mo> <mi mathvariant="normal">Δ</mi> <msub> <mi>S</mi> <mi>m</mi> </msub> </mrow> </math></EquationSource> </InlineEquation>). Our temperature-dependent magnetization analysis reveals a second-order phase transition from the ferromagnetic (FM) to the paramagnetic (PM) phase at 208&#xa0;K, consistent with previous theoretical and experimental findings. The maximum magnetic entropy change (<InlineEquation ID="IEq5"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="10948_2025_6970_Article_IEq5.gif" Format="GIF" Height="18" Rendition="HTML" Resolution="72" Type="Linedraw" Width="63" /> </InlineMediaObject> <EquationSource Format="TEX">\(-\Delta S_m^{\text {max}}\)</EquationSource> <EquationSource Format="MATHML"><math> <mrow> <mo>-</mo> <mi mathvariant="normal">Δ</mi> <msubsup> <mi>S</mi> <mi>m</mi> <mtext>max</mtext> </msubsup> </mrow> </math></EquationSource> </InlineEquation>) is 6.46&#xa0;J/kg.K at 208&#xa0;K under a 5&#xa0;T magnetic field, with a corresponding relative cooling power (RCP) of 680.11&#xa0;J/kg. Additionally, hysteresis behavior is observed at various temperatures. These findings suggest that Gd<InlineEquation ID="IEq6"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="10948_2025_6970_Article_IEq6.gif" Format="GIF" Height="10" Rendition="HTML" Resolution="72" Type="Linedraw" Width="8" /> </InlineMediaObject> <EquationSource Format="TEX">\(_3\)</EquationSource> <EquationSource Format="MATHML"><math> <mmultiscripts> <mrow /> <mn>3</mn> <mrow /> </mmultiscripts> </math></EquationSource> </InlineEquation>In is a promising candidate for magnetic refrigeration applications.</p>

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Computational Insights into the Magnetocaloric Effect and Magnetic Properties of Gd\(_3\)In Compound for Magnetic Refrigeration Applications

  • H. Kerrai,
  • E. M. Jalal,
  • H. Saadi,
  • M. Salama,
  • M. Kerouad,
  • A. Zaim

摘要

This manuscript investigates the magnetocaloric effect and magnetic properties of the Gd \(_3\) 3 In compound as functions of magnetic field and temperature using a mean-field approximation. We first introduce the model and methodology, followed by the determination of the transition temperature through the analysis of magnetization, susceptibility, and magnetic entropy change ( \(-\Delta S_m\) - Δ S m ). Our temperature-dependent magnetization analysis reveals a second-order phase transition from the ferromagnetic (FM) to the paramagnetic (PM) phase at 208 K, consistent with previous theoretical and experimental findings. The maximum magnetic entropy change ( \(-\Delta S_m^{\text {max}}\) - Δ S m max ) is 6.46 J/kg.K at 208 K under a 5 T magnetic field, with a corresponding relative cooling power (RCP) of 680.11 J/kg. Additionally, hysteresis behavior is observed at various temperatures. These findings suggest that Gd \(_3\) 3 In is a promising candidate for magnetic refrigeration applications.