<p>Enhancing the capacitance and rate performance of carbon-based electrodes in supercapacitors is a significant problem for commercial feasibility. To fulfil these specifications, Ti₃C₂Tx (MXene)/reduced graphene oxide (RGO) electrodes were synthesised by a one-step hydrothermal process followed by carbonisation for use as supercapacitor electrodes. The physico-chemical characteristics of the electrodes are characterised by X ray diffraction (XRD), Scanning electron microscope (SEM), Raman spectroscopy, N₂ adsorption-desorption and X-ray photoelectron spectra (XPS) analysis. The Ti₃C₂Tx MXene/RGO exhibits a capacitance of 335 Cg^− 1 at 1 Ag^− 1 in a 1&#xa0;M KOH electrolyte, maintaining 305 Cg^− 1 at 5&#xa0;A g^− 1, along with a commendable lifespan. Furthermore, the constructed asymmetric device exhibited a substantial potential window (1.5&#xa0;V) and a significant specific capacitance (235 Cg^− 1 at 1&#xa0;A g^− 1). Furthermore, the ASC device has a substantial energy density of around 32.4 Wh kg^− 1, with a power density of 2917&#xa0;W kg^− 1, and demonstrates prolonged stability with around 82% retention after 10,000 cycles. The proposed method provides an alternate technique for fabricating stretchable MXene-based energy storage devices and may be applied to additional members of the extensive MXene family.</p>