<p>Elemental and Sr isotopic (<sup>87</sup>Sr/<sup>86</sup>Sr) distributions in multiple mineralogical phases of lake sediments are modulated by catchment processes, but their controlling mechanisms and paleoenvironmental indications remain poorly understood. This study employs a 20-step incremental leaching approach to analyze the distribution of elements and <sup>87</sup>Sr/<sup>86</sup>Sr ratios in carbonate-rich lake sediments. Targeted phases include water-soluble salts (water leaching), exchangeable phase (NH<sub>4</sub>Ac leaching), carbonates (incremental HOAc leaching), Fe–Mn oxides (NH<sub>2</sub>OH·HCl leaching), chlorite phase (heated HCl leaching), and residual silicates (HF-HNO<sub>3</sub> digestion). Our results reveal that most elements peak in residual silicate phase, while other phases exhibit distinct elemental preferences: Na, K, Ca, Rb and Sr in water-soluble salts; Ca, Sr, Mn, and P in exchangeable phase; Ca, Sr, Mg, Mn and P in carbonate phase; Fe, Mn, Mg, Sr and P in Fe–Mn oxide phase; and K, Fe, Mg, Mn, Rb, Sr and P in chlorite phase. The <sup>87</sup>Sr/<sup>86</sup>Sr ratios exhibit consistently low values of 0.7111–0.7114 in water-soluble, exchangeable, and carbonate phases (leached by 0.25 and 1% HOAc), then gradually increase to 0.7129–0.7133 through the subsequent extraction of carbonate and Fe–Mn oxides, followed by a sharp increase to 0.7218–0.7263 at chlorite and residual silicate phases. Our study reveals that the elemental and <sup>87</sup>Sr/<sup>86</sup>Sr data primarily reflect a mixture of authigenic (lake water) and detrital signals. Our results, therefore, suggest that when carbonate is exhausted during leaching, non-carbonate inputs are significant and that the original <sup>87</sup>Sr/<sup>86</sup>Sr signature of the paleolake water can be uniformly extracted from the water-soluble, exchangeable, and initially dissolved carbonate fractions when diagenetic alteration is carefully considered.</p>

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Unraveling paleoenvironmental signals in carbonate-rich lake sediments from the Qaidam Basin: insights from elemental and 87Sr/86Sr ratios using a sequential leaching approach

  • Zhongyi Yan,
  • Yahui Yue,
  • Guohan Du,
  • Jiajun He,
  • Xin Zhao,
  • Wenjing Zhu,
  • Yudong Liu,
  • Yibo Yang

摘要

Elemental and Sr isotopic (87Sr/86Sr) distributions in multiple mineralogical phases of lake sediments are modulated by catchment processes, but their controlling mechanisms and paleoenvironmental indications remain poorly understood. This study employs a 20-step incremental leaching approach to analyze the distribution of elements and 87Sr/86Sr ratios in carbonate-rich lake sediments. Targeted phases include water-soluble salts (water leaching), exchangeable phase (NH4Ac leaching), carbonates (incremental HOAc leaching), Fe–Mn oxides (NH2OH·HCl leaching), chlorite phase (heated HCl leaching), and residual silicates (HF-HNO3 digestion). Our results reveal that most elements peak in residual silicate phase, while other phases exhibit distinct elemental preferences: Na, K, Ca, Rb and Sr in water-soluble salts; Ca, Sr, Mn, and P in exchangeable phase; Ca, Sr, Mg, Mn and P in carbonate phase; Fe, Mn, Mg, Sr and P in Fe–Mn oxide phase; and K, Fe, Mg, Mn, Rb, Sr and P in chlorite phase. The 87Sr/86Sr ratios exhibit consistently low values of 0.7111–0.7114 in water-soluble, exchangeable, and carbonate phases (leached by 0.25 and 1% HOAc), then gradually increase to 0.7129–0.7133 through the subsequent extraction of carbonate and Fe–Mn oxides, followed by a sharp increase to 0.7218–0.7263 at chlorite and residual silicate phases. Our study reveals that the elemental and 87Sr/86Sr data primarily reflect a mixture of authigenic (lake water) and detrital signals. Our results, therefore, suggest that when carbonate is exhausted during leaching, non-carbonate inputs are significant and that the original 87Sr/86Sr signature of the paleolake water can be uniformly extracted from the water-soluble, exchangeable, and initially dissolved carbonate fractions when diagenetic alteration is carefully considered.