Green Synthesis of Nanocellulose-Based Ag@CuO Nanocomposites and its Evaluation for Photocatalytic, Antibacterial Activity and Antioxidant Activity
摘要
In this study, an environmentally friendly green method was successfully used for the formation of Ag@CuO/CNC nanocomposites of various compositions. Comprehensive analysis using UV-Vis, FTIR, NTA, SEM, TEM, and XPS confirmed that well-integrated Ag and CuO nanoparticles were successfully formed inside the matrix of cellulose nanocrystals (CNCs). CNC effectively provides a solid support and supporting surface for the nanocomposites, as shown by the structural, morphological, and compositional studies that showed uniform dispersion of the metal/metal oxide particles. The synergistic interaction between Ag and CuO significantly enhanced the functionality of the nanocomposites. Ag25@CuO75/CNC had the best photocatalytic activity among all the compositions, degrading methylene blue by around 88.33%, mainly as a result of increased reactive species formation and charge separation. Ag75@CuO25/CNC, on the other hand, exhibited the highest antioxidant activity and antibacterial performance among all of the prepared samples, with a maximum zone of inhibition of around 16.26 mm. These findings illustrate that changing the Ag@CuO composition can thoroughly enhance photocatalytic, antibacterial, and antioxidant properties, which makes Ag@CuO/CNC nanocomposites significant material for biomedical and environmental applications.
Graphical Abstract