<p>This work delineates a simple and efficient method for synthesizing a hybrid material comprising Ag₂MoO₄ nanoparticles anchored on nitrogen-doped reduced graphene oxide (AMO/NRGO) for high-performance supercapacitor applications. The synthesized compounds were validated and characterized using structural, functional, nitrogen adsorption–desorption, surface, elemental analysis, and electrochemical assessments. The AMO/NRGO hybrid electrode has exceptional electrochemical characteristics, with a specific capacitance of 456 Fg⁻¹ at a current density of 1 Ag⁻¹ and 231 Fg⁻¹ at 1 Ag⁻¹, along with extraordinary cycle stability, retaining 93.5% of its specific capacitance after 5000 cycles. Consequently, the AMO/NRGO composite may serve as a promising electrode material for future energy applications. The asymmetric supercapacitor (ASC) using AMO/NRGO//AC electrodes demonstrates exceptional capacitive performance (275 Fg⁻¹ at 1 Ag⁻¹) and superior cycle stability (90.5% at 1 Ag⁻¹ after 5000 cycles). The ASC demonstrated an energy density of 48.5 Wh kg⁻¹ at a power density of 976 W kg−1. Consequently, AMO/NRGO//AC ASC is anticipated to be an advantageous material for high-performance applications involving energy storage.</p>