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Facile Hydrothermal Synthesis of ZnCo2O4 Hexagonal Plate-Like Electrode for Supercapacitor Applications: Capacitive and Diffusive Mechanism of Trassati Method

  • M. Silambarasan,
  • R. Boopathiraja,
  • Surekha Podili,
  • V. Kavitha,
  • Nouf H. Alotaibi,
  • Saikh Mohammad,
  • B. Sethuraman,
  • K. Sakthipandi

摘要

The Zinc cobaltite (ZnCo2O4), with its extensive redox reactions involving many ions and oxidation states, is an emerging electrode material for supercapacitors. The ZnCo2O4 prepared by using easy hydrothermal method. The generated material’s structural, morphological, textural, and electrochemical behaviour were analysed using XRD, FESEM, XPS, Raman, FTIR, BET, CV, GCD, and EIS. The prepared ZnCo2O4 material exhibits bundle of hexagonal plates (HPs) like structure. The prepared ZnCo2O4 HPs electrode delivers high specific capacitance of 950 Fg− 1 at 5 mA. The prepared ZnCo2O4 HPs electrode exhibits capacity retention of 74.2% after 6500 cycles. ZnCo2O4 HPs electrode exhibits energy density of 21.1 Whkg− 1 and power density of 446.8 Wkg− 1at 5 mA. The findings show that ZnCo2O4 HPs have a great deal of promise for application as an effective supercapacitive electrode material because of their higher specific capacitance and increased cycle stability.