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Synthesis and Properties of Manganese(II) and Nickel(II) 1-D Coordination Polymers Based on 2,5-di-hydroxy-3,6-di-tert-butyl-para-quinone

  • 期刊论文

  • 发表日期：

    2024年2月5日

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  • Olesya Yu. Trofimova,
  • Irina V. Ershova,
  • Arina V. Maleeva,
  • Anton V. Cherkasov,
  • Mikhail N. Khrizanforov,
  • Konstantin A. Kovalenko,
  • Artem S. Bogomyakov,
  • Alexandr V. Piskunov

摘要

New manganese(II) and nickel(II) 1-D zigzag coordination polymers [M2+(pQ2−)·2(solv)]n (M2+ = Mn2+, solv = N,N’-dimethylacetamide (1) and M = Ni2+, solv = N,N’-dimethylformamide (2); pQ2− - dianionic form of 2,5-di-hydroxy-3,6-di-tert-butyl-para-quinone) have been synthesized and characterized. Both compounds 1 and 2 are isomorphic. Their physicochemical properties such as thermal stability, gas sorption, redox and magnetic properties are described.