Scholarlink

<p>A new tetrameric complex of Ba(II), [Ba<sub>4</sub>(PA)<sub>4</sub>(H<sub>2</sub>O)<sub>20</sub>]·4H<sub>2</sub>O (PA = pamoate) has been prepared by gel diffusion technique at ambient condition. The grown crystals were characterized by elemental analysis, single crystal X-ray diffraction studies, thermogravimetry, FT-IR and UV–visible spectral studies. The single crystal X-ray diffraction studies show that the crystal structure consists of two different types of nine coordinated Ba centers (Ba1 and Ba2). In addition to the carboxylate groups of pamoate, two coordinated water also interconnect the Ba(II) centers. The carboxylate groups of pamoate exhibit monodentate, bismonodentate and bidentate, coordination modes with Ba(II) ions. Hydrogen bonding further stabilizes the crystal structure. Photoluminescence studies were also carried out.</p> Graphical Abstract <p></p> <p>A new tetrameric complex of Ba(II) with pamoic acid (H<sub>2</sub>PA) of formula [Ba<sub>4</sub>(PA)<sub>4</sub>(H<sub>2</sub>O)<sub>20</sub>]·4H<sub>2</sub>O (BaPA) has been prepared by gel diffusion technique at ambient condition and is characterized by various analytical techniques.</p>

错误：搜索内容不能为空，请输入英文关键词
错误：关键词超出字数限制，请精简
高级检索

Crystal Growth and Characterization of a New Tetrameric Complex of Ba(II) with Pamoic Acid

  • 期刊论文

  • 发表日期：

    2025年8月13日

查看全文
  • S. Shibu Prasad

摘要

A new tetrameric complex of Ba(II), [Ba4(PA)4(H2O)20]·4H2O (PA = pamoate) has been prepared by gel diffusion technique at ambient condition. The grown crystals were characterized by elemental analysis, single crystal X-ray diffraction studies, thermogravimetry, FT-IR and UV–visible spectral studies. The single crystal X-ray diffraction studies show that the crystal structure consists of two different types of nine coordinated Ba centers (Ba1 and Ba2). In addition to the carboxylate groups of pamoate, two coordinated water also interconnect the Ba(II) centers. The carboxylate groups of pamoate exhibit monodentate, bismonodentate and bidentate, coordination modes with Ba(II) ions. Hydrogen bonding further stabilizes the crystal structure. Photoluminescence studies were also carried out.

Graphical Abstract

A new tetrameric complex of Ba(II) with pamoic acid (H2PA) of formula [Ba4(PA)4(H2O)20]·4H2O (BaPA) has been prepared by gel diffusion technique at ambient condition and is characterized by various analytical techniques.