Scholarlink

<p>Lithiated N-(2,6-diisopropylphenyl)-[6-(2,4,6-triisopropylphenyl)-pyridine-2-yl]-amine (ApH) undergoes a salt metathesis reaction with MnBr<sub>2</sub> in tetrahydrofuran (THF) at 50&#xa0;°C in the presence of two equivalents of 4-<i>tert</i>-butylpyridine (<sup><i>t</i></sup>BuPy) to yield only the second example of mononuclear manganese aminopyridinates, [Mn(Ap)<sub>2</sub>(<sup><i>t</i></sup>BuPy)]. The compound [C<sub>59</sub>H<sub>71</sub>MnN<sub>5</sub>], crystallized in the monoclinic space group, <i>P</i>2<sub>1</sub>/<i>c</i> with unit cell parameters: a = 11.9650(5) b = 17.9530(7) c = 24.3110(10) Å, β = 95.081(3)°, V = 5201.7(4) A<sup>3</sup>, Z = 4. Hirshfeld analyses show that H⋯H (89.1%) and H⋯C/C⋯H (10.9%) interactions are the two main contributors that lead to intermolecular stabilization in the solid-state structure.</p>

错误：搜索内容不能为空，请输入英文关键词
错误：关键词超出字数限制，请精简
高级检索

A Rare Example of Manganese Aminopyridinate – Synthesis and Structure

  • 期刊论文

  • 发表日期：

    2025年1月8日

查看全文
  • Awal Noor

摘要

Lithiated N-(2,6-diisopropylphenyl)-[6-(2,4,6-triisopropylphenyl)-pyridine-2-yl]-amine (ApH) undergoes a salt metathesis reaction with MnBr2 in tetrahydrofuran (THF) at 50 °C in the presence of two equivalents of 4-tert-butylpyridine (tBuPy) to yield only the second example of mononuclear manganese aminopyridinates, [Mn(Ap)2(tBuPy)]. The compound [C59H71MnN5], crystallized in the monoclinic space group, P21/c with unit cell parameters: a = 11.9650(5) b = 17.9530(7) c = 24.3110(10) Å, β = 95.081(3)°, V = 5201.7(4) A3, Z = 4. Hirshfeld analyses show that H⋯H (89.1%) and H⋯C/C⋯H (10.9%) interactions are the two main contributors that lead to intermolecular stabilization in the solid-state structure.