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A New Polymorph of tert-Butyl (2-Aminophenyl)Carbamate

  • Zoe E. Potter,
  • Max T. Hill,
  • Jonathan D. Sellars,
  • Paul G. Waddell

摘要

A new polymorph of tert-butyl (2-aminophenyl)carbamate was identified using single crystal X-ray diffraction. The compound crystallised in the centrosymmetric, monoclinic space group P21/n with an asymmetric unit comprising two crystallographically-independent molecules (Zʹ = 2). This new structure was compared to that of the known polymorph with the differences between the two being attributed to a combination of space group symmetry, conformational variation, hydrogen bonding network dimensionality and crystal packing.