Cementitious electromagnetic wave absorbers: a multi-scale design framework for structural composites
摘要
The escalating problem of electromagnetic pollution calls for structural materials that integrate wave absorption with mechanical robustness. This review presents a multi-scale design framework that integrates microscale loss mechanisms, mesoscale filler/pore engineering, and macroscale structural wave interference—a departure from compartmentalized approaches. Key findings reveal systematic trade-offs. For porous foams, ultra-broadband absorption (EAB up to 14.8 GHz) comes at the cost of low compressive strength (< 10 MPa). In contrast, 3D gradient structures maintain high strength (> 44 MPa) while providing broadband absorption. Furthermore, designs that achieve > 14 GHz bandwidth together with > 40 MPa strength are now feasible. Persistent challenges include low-frequency performance, alkali durability, and scalable fabrication. The review concludes by presenting transformative pathways that leverage AI-guided design, cement-specific additive manufacturing, and sustainable material cycles. These pathways offer a systematic conceptual framework for intelligent, structurally integrated cement-based metamaterials.