Effects of Ag2S addition on the transition temperature, Josephson current and AC susceptibility of YBa2Cu3O7−δ superconductor
摘要
The effects of Ag2S addition on the electrical transport properties, microstructure, AC susceptibility and Josephson current of YBa2Cu3O7−δ were investigated. Samples with the starting composition YBa2Cu3O7−δ(Ag2S)x for x = 0, 1, 2, 5, 10, 20 and 50 wt.% were prepared using the solid state reaction method. X-ray diffraction, four-point-probe electrical resistance measurements, field emission scanning electron microscopy (SEM) and AC susceptibility techniques were used to characterize the samples. The orthorhombic structure of YBa2Cu3O7−δ was preserved upon Ag2S addition. SEM micrographs showed that the average grain size of the x = 10 wt.% sample decreased with Ag2S addition. Ag2S did not suppress the onset-transition temperature, Tc-onset; however, it reduced the zero-resistance temperature, Tc-zero. The intergranular peak temperature (Tp1) and intragranular peak temperature (Tp2) were determined from the imaginary part of the AC susceptibility. The superconducting transition temperature from AC susceptibility measurements, Tcχ′, defined as the onset of the diamagnetic transition in the real component (χ′) of the AC susceptibility, did not change significantly; however, Tp1 and Tp2 decreased significantly with increasing Ag₂S content. The critical current densities Jc(Tp2) ranged from 21.7 to 23.2 A cm−2. The Josephson energy (EJ) reached its maximum value for the x = 1 wt.% sample, indicating enhanced intergrain coupling at this composition. This addition level optimizes Josephson coupling between YBa₂Cu₃O₇−δ grains, which may be useful for designing high-coherence qubits based on granular high-Tc superconductors. Compared with other compound additions having different magnetic properties, Ag₂S addition results in comparatively less suppression of the superconducting transition temperature in YBa2Cu3O7−δ.