<p>The mid-to-far-infrared wave is an electromagnetic wave with a wavelength range of 5 − 1000&#xa0;μm, significant for remote sensing, object identification, chemical sensing, missile defence, and weather monitoring. Various methods provide dual infrared band detection; however, their high cost, complexity, and requirement for active cooling hinder broad implementation. This study utilises the benefits of colloidal quantum dot composite for the advancement of dual-wave infrared band detectors. We present the structural, compositional, morphological, spectroscopic, and electrical characteristics of colloidal Ag<sub>₂</sub>S/PbS quantum dot (CQD) composites. The carrier concentration value 2.032 <InlineEquation ID="IEq1"> <EquationSource Format="TEX">\(\times\)</EquationSource> <EquationSource Format="MATHML"><math> <mo>×</mo> </math></EquationSource> </InlineEquation> 10<sup>20&#xa0;</sup>cm<sup>⁻3</sup> from capacitance–voltage measurement was determined and it aligns with the carrier concentration derived from the Hall measurement. The fabricated ITO/Ag<sub>₂</sub>S + PbS/Ag photodetector device yielded a photocurrent density 0.04&#xa0;mA/cm<sup>2</sup> under dark condition and 0.24–34&#xa0;mA/cm<sup>2</sup> under 980&#xa0;nm to 15&#xa0;μm wavelength illumination respectively, resulting in increased photocurrent relative to dark current at room temperature. This configuration promotes a double Schottky barrier with an ideality factor of 1.01, indicative of optimal Schottky behaviour in photodiodes. The figure of merit sensitivity (S%), photo responsivity (R), and D* are 48%, 9.64&#xa0;mA/W, and 2.5 × 10<sup>9</sup> Jones, respectively. The external quantum efficiency (EQE%) measured at -10 °C, 0 °C, and 10 °C is 52.7%, 34.9% and 12.2%, respectively, facilitating the design of photodetector which can work at both low and room temperature using a dual-band IR active device. The outcomes of this FOM are influenced by characteristics such as quantum dot size, temperature, and the concentration percentage of Ag<sub>₂</sub>S.</p>

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Ag2S/PbS colloidal quantum dots composite for mid-to-far wave IR detection

  • Sulthana T Tabassum,
  • Gajanan V. Honnavar

摘要

The mid-to-far-infrared wave is an electromagnetic wave with a wavelength range of 5 − 1000 μm, significant for remote sensing, object identification, chemical sensing, missile defence, and weather monitoring. Various methods provide dual infrared band detection; however, their high cost, complexity, and requirement for active cooling hinder broad implementation. This study utilises the benefits of colloidal quantum dot composite for the advancement of dual-wave infrared band detectors. We present the structural, compositional, morphological, spectroscopic, and electrical characteristics of colloidal AgS/PbS quantum dot (CQD) composites. The carrier concentration value 2.032 \(\times\) × 1020 cm⁻3 from capacitance–voltage measurement was determined and it aligns with the carrier concentration derived from the Hall measurement. The fabricated ITO/AgS + PbS/Ag photodetector device yielded a photocurrent density 0.04 mA/cm2 under dark condition and 0.24–34 mA/cm2 under 980 nm to 15 μm wavelength illumination respectively, resulting in increased photocurrent relative to dark current at room temperature. This configuration promotes a double Schottky barrier with an ideality factor of 1.01, indicative of optimal Schottky behaviour in photodiodes. The figure of merit sensitivity (S%), photo responsivity (R), and D* are 48%, 9.64 mA/W, and 2.5 × 109 Jones, respectively. The external quantum efficiency (EQE%) measured at -10 °C, 0 °C, and 10 °C is 52.7%, 34.9% and 12.2%, respectively, facilitating the design of photodetector which can work at both low and room temperature using a dual-band IR active device. The outcomes of this FOM are influenced by characteristics such as quantum dot size, temperature, and the concentration percentage of AgS.