Boosting screen-printing and microwave electrical performance of copper paste for LTCC applications through rheological control
摘要
Copper electrode pastes for LTCC applications have advantages of high electrical conductivity and low cost. In this work, a novel Poly (propylene carbonate) (PPC) organic vehicle is developed, and its effects on rheological characteristics, screen-printing properties, and microwave electrical performance of copper paste are systematically investigated. PPC organic vehicle imparts ideal pseudoplasticity and thixotropy to copper paste, enabling precise screen-printing of fine lines below 40 μm and forming an excellent surface morphology. Moreover, PPC organic vehicle decomposes completely in nitrogen atmosphere without carbon residues. Copper electrode exhibits an ultra-low sheet resistance of 0.4 mΩ/□, along with outstanding high-frequency performance, including a skin conductivity close to 64% of the theoretical value and a high Q-factor of 4964. This work achieves a synergistic improvement in screen-printing compatibility and microwave electrical performance in copper electrode paste, providing a reliable material solution for the high-performance LTCC components.