Scholarlink

<p>The synthesis process significantly influences the morphology and electrochemical properties of electrode materials, and the potential for sustainable alternatives is assessed by comparing their electrochemical properties. BiVO<sub>4</sub> nanoparticles were synthesized using both the environmentally friendly green method of flaxseed (Linum usitatissimum) extract and conventional chemical methods; hexamethylenetetramine (HMTA) was used as a surfactant. Both samples exhibited a monoclinic scheelite phase in XRD analysis, with average crystallite sizes of 13.96&#xa0;nm (green) and 15.94&#xa0;nm (chemical). In the FESEM images, irregular spherical morphology was observed in green synthesis. The specific capacitance of the green-synthesized BiVO<sub>4</sub> nanoparticles was 2366.24 F/g at 3 A/g, which was higher than that of the chemically synthesized BiVO<sub>4</sub> at the same current density, which was 1273 F/g. Cyclic stability and excellent capacitance retention of 89.43% were obtained over 5000 cycles of charge–discharge curves of the green-synthesized BiVO<sub>4</sub> are a potential electrode material for energy storage devices.</p>

错误：搜索内容不能为空，请输入英文关键词
错误：关键词超出字数限制，请精简
高级检索

Comparative study on the electrochemical properties of bismuth vanadate (BiVO4) nanoparticles synthesized via green and chemical methods

  • 期刊论文

  • 发表日期：

    2026年2月24日

查看全文
  • N. Kartheeswari,
  • B. Gayathri Manju

摘要

The synthesis process significantly influences the morphology and electrochemical properties of electrode materials, and the potential for sustainable alternatives is assessed by comparing their electrochemical properties. BiVO4 nanoparticles were synthesized using both the environmentally friendly green method of flaxseed (Linum usitatissimum) extract and conventional chemical methods; hexamethylenetetramine (HMTA) was used as a surfactant. Both samples exhibited a monoclinic scheelite phase in XRD analysis, with average crystallite sizes of 13.96 nm (green) and 15.94 nm (chemical). In the FESEM images, irregular spherical morphology was observed in green synthesis. The specific capacitance of the green-synthesized BiVO4 nanoparticles was 2366.24 F/g at 3 A/g, which was higher than that of the chemically synthesized BiVO4 at the same current density, which was 1273 F/g. Cyclic stability and excellent capacitance retention of 89.43% were obtained over 5000 cycles of charge–discharge curves of the green-synthesized BiVO4 are a potential electrode material for energy storage devices.