Impact of ultra-thin titanium film thickness on titanium silicides: specific contact resistivity and thermal stability
摘要
High specific contact resistivity (ρc) and anneal-induced parasitic resistance (Rparasitic) are major challenges for downscaled DRAM peripheral transistors. Here, the effects of ultra-thin Ti and TiN thickness on the ρc of TiSix/n⁺-Si ohmic contacts and on their thermal stability are systematically investigated as a function of annealing temperature and duration. The results show that ρc is strongly dependent on Ti thickness, whereas it is only weakly affected by TiN thickness. A Ti/TiN bilayer of 50 Å/50 Å achieves ρc on the order of 10⁻⁸ Ω·cm2 after a DRAM-relevant anneal of 750 °C for 30 min. Oxygen gettering and redistribution in the Ti layer are discussed as the primary mechanism responsible for the observed trends.