<p>1,5,7-Triazabicyclo[4.4.0]dec-5-ene (TBD) as an organic base with high catalytic efficiency and excellent compatibility with epoxy resin (EP), is widely used as a catalyst for ester exchange reactions to enhance the dynamic restructuring of the network. However, it will be involved in the curing process, change the cross-linked structure, and affect the properties of the material. In this paper, the effect of TBD on the dynamic, physicochemical, and dielectric properties of dual-cured epoxy resin was investigated, the method of TBD to enhance the dynamic reorganization of dual-cured epoxy resin network was proposed, the mechanical and dielectric properties of TBD composite dual-cured epoxy resin were studied, and the synergistic relationship between TBD and pressure of dual-cured epoxy resin explored. It shows that TBD enhanced the viscoelastic behavior, shortened the stress relaxation time, lowered the topological freezing transition temperature (<i>T</i>_<i>v</i>), and improved the dynamic network reorganization efficiency of dual-cured epoxy resin, but TBD reduced its thermal stability and affected the mechanical and dielectric properties. TBD enhanced the network reorganization ability of recycled dual-cured epoxy resin, improved the interfacial healing effect, and enhanced the mechanical and dielectric properties of recycled dual-cured epoxy resin. However, the enhancement effect of TBD was weakened with the increase of hot-pressing pressure, and the excessive amount of TBD would destroy the network structure, resulting in the decrease of the mechanical and dielectric properties of the recycled dual-cured epoxy resin. The above shows that we have developed a low-energy and high-efficiency network dynamic reconfiguration enhancement method, which is important for guiding the industrial scale-up of thermal pressure recovery.</p>