<p>The development of innovative and effective photocatalysts has garnered considerable scientific interest in recent years, aimed at achieving ecologically sustainable solution. We synthesized Ag<sub>2</sub>O nanoparticles-anchored g-C<sub>3</sub>N<sub>4</sub>/AC photocatalyst using Sol-gel method and examined its photocatalytic degradation efficiency against the antibiotic-Amoxicillin. The synthesized catalyst underwent comprehensive characterization through various analytical techniques, such as XRD, FT-IR, SEM, EDX, TEM, XPS, UV-visible DRS, PL, BET, and EIS. The findings indicate that the Ag<sub>2</sub>O nanoparticles are effectively distributed on g-C<sub>3</sub>N<sub>4</sub>/AC, producing the ternary Ag<sub>2</sub>O/g-C<sub>3</sub>N<sub>4</sub>/AC nanocomposite that demonstrates superior photocatalysis over pristine g-C<sub>3</sub>N<sub>4</sub> nanoparticles. The Ag<sub>2</sub>O/g-C<sub>3</sub>N<sub>4</sub>/AC composite exhibited a degradation efficiency of aproximately 95.98% following 70&#xa0;min of UV-visible light irradiation. Kinetic experiments demonstrated pseudo-first-order behaviour, with the composite showing over a threefold increase in the apparent rate constant relative to pristine g-C<sub>3</sub>N<sub>4</sub>. Stability and reusability assessments demonstrated exceptional photostability, with only negligible efficiency reduction after four consecutive cycles. Scavenger tests revealed that the degradation process is predominantly regulated by O<sub>2</sub><sup>·−</sup> and <sup>·</sup>OH active species, while photoexcited h⁺ plays a minor role. The improved separation of photo-induced charge carriers in Ag<sub>2</sub>O/g-C<sub>3</sub>N<sub>4</sub>/AC photocatalyst significantly improved the photocatalytic degradation of AMX. This research demonstrates the exceptional performance of Ag<sub>2</sub>O/g-C<sub>3</sub>N<sub>4</sub>/AC as a photocatalyst for the degradation of AMX, providing a practical solution for wastewater clean-up.</p> Graphical Abstract <p></p>

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Sol-gel synthesis of ternary Ag2O/g-C3N4/AC photocatalyst: characterization, photocatalytic removal of amoxicillin and its mechanistic insights

  • Kamal Chitalkar,
  • Dinesh Hase,
  • Kailas Kadam,
  • Kanhaiyalal Bhavsar,
  • Vaishali Murade,
  • Haribhau Aher

摘要

The development of innovative and effective photocatalysts has garnered considerable scientific interest in recent years, aimed at achieving ecologically sustainable solution. We synthesized Ag2O nanoparticles-anchored g-C3N4/AC photocatalyst using Sol-gel method and examined its photocatalytic degradation efficiency against the antibiotic-Amoxicillin. The synthesized catalyst underwent comprehensive characterization through various analytical techniques, such as XRD, FT-IR, SEM, EDX, TEM, XPS, UV-visible DRS, PL, BET, and EIS. The findings indicate that the Ag2O nanoparticles are effectively distributed on g-C3N4/AC, producing the ternary Ag2O/g-C3N4/AC nanocomposite that demonstrates superior photocatalysis over pristine g-C3N4 nanoparticles. The Ag2O/g-C3N4/AC composite exhibited a degradation efficiency of aproximately 95.98% following 70 min of UV-visible light irradiation. Kinetic experiments demonstrated pseudo-first-order behaviour, with the composite showing over a threefold increase in the apparent rate constant relative to pristine g-C3N4. Stability and reusability assessments demonstrated exceptional photostability, with only negligible efficiency reduction after four consecutive cycles. Scavenger tests revealed that the degradation process is predominantly regulated by O2·− and ·OH active species, while photoexcited h⁺ plays a minor role. The improved separation of photo-induced charge carriers in Ag2O/g-C3N4/AC photocatalyst significantly improved the photocatalytic degradation of AMX. This research demonstrates the exceptional performance of Ag2O/g-C3N4/AC as a photocatalyst for the degradation of AMX, providing a practical solution for wastewater clean-up.

Graphical Abstract