<p>In this study, the microstructural evolution and corrosion product layer characteristics of Inconel 625 alloy subjected to different solution treatment temperatures in a simulated oilfield environment were investigated, and their influence on corrosion resistance was analysed. The results indicate that after solution treatment in the range of 950–1100&#xa0;°C, the Mo-rich M<sub>6</sub>C carbides and Cr-rich M<sub>23</sub>C<sub>6</sub> carbides gradually dissolve into the γ matrix, weakening the grain-boundary pinning effect of the carbides and promoting grain growth. Electrochemical measurements revealed that the corrosion current density and charge carrier density of Inconel 625 first decreased but then increased with increasing grain size. In the high temperature and high pressure CO<sub>2</sub> environment, the alloy treated at 1050&#xa0;°C has better corrosion resistance, which is attributed to the dissolution of M<sub>6</sub>C and M<sub>23</sub>C<sub>6</sub> carbides into the matrix, resulting in an increase in the content of dense Cr<sub>2</sub>O<sub>3</sub>-based oxides. It effectively inhibits the penetration of Cl<sup>−</sup> and enhances the pitting corrosion resistance.</p>

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Corrosion behavior of Inconel 625 alloy in high-temperature and high-pressure CO2 environment

  • Yuqi Hao,
  • Xinyi Liu,
  • Wen Xi,
  • Bo Luan,
  • Honglei Wang,
  • Xingcheng Qiu,
  • Jin Li,
  • Xu Wang,
  • Jacob C. Huang

摘要

In this study, the microstructural evolution and corrosion product layer characteristics of Inconel 625 alloy subjected to different solution treatment temperatures in a simulated oilfield environment were investigated, and their influence on corrosion resistance was analysed. The results indicate that after solution treatment in the range of 950–1100 °C, the Mo-rich M6C carbides and Cr-rich M23C6 carbides gradually dissolve into the γ matrix, weakening the grain-boundary pinning effect of the carbides and promoting grain growth. Electrochemical measurements revealed that the corrosion current density and charge carrier density of Inconel 625 first decreased but then increased with increasing grain size. In the high temperature and high pressure CO2 environment, the alloy treated at 1050 °C has better corrosion resistance, which is attributed to the dissolution of M6C and M23C6 carbides into the matrix, resulting in an increase in the content of dense Cr2O3-based oxides. It effectively inhibits the penetration of Cl and enhances the pitting corrosion resistance.