Hierarchically structured superhydropobic polydimethylsiloxane composite film for daytime radiative cooling
摘要
Radiative cooling without energy consumption is an ideal green alternative for air conditioning. Herein, we fabricate a hierarchically structured superhydrophobic composite film of polydimethylsiloxane, hollow glass beads and silica aerogels (S-PDMS/HGB/SSA) which integrates strong sunlight reflectance (95.3%), high thermal infrared emittance (96.9%) and robust superhydrophobicity (160.9°). The effective synergy of the high solar reflection and thermal infrared emission allows the coating to achieve a sub-ambient temperature drop of 7.4 °C under strong sunlight. The superhydrophobicity keeps the composite film away from contamination by self-cleaning, maintaining well the radiative cooling performance for long-term outdoor application. Additionally, the as prepared film demonstrates excellent chemical durability after exposure to different pH solutions and UV light irradiation. This work provides a new strategy to integrate self-cleaning with radiative cooling, showing great potential to advance energy-free cooling materials toward real-world applications.