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<p>The first application of the Claisen rearrangement of resorcinarene derivatives is described. Optimisation of this reaction allowed the preparation of gram-quantities of the Claisen-rearranged product in yields greater than 80% over two simple synthetic steps from the parent resorcinarenes. Microwave assisted solventless rearrangement was also investigated. These novel resorcinarenes have been characterized by crystallographic methods, in addition to the standard spectroscopic techniques.</p>

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Synthesis and structural characterisation of new resorcinarenes via Claisen rearrangement

  • 期刊论文

  • 发表日期：

    2026年6月3日

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  • Cristina Adriana Macarov,
  • Daniel A. Tan,
  • Mauro Mocerino,
  • Stephen A. Moggach,
  • Mark I. Ogden,
  • Philip C. Bulman Page,
  • Alexandra M. Z. Slawin

摘要

The first application of the Claisen rearrangement of resorcinarene derivatives is described. Optimisation of this reaction allowed the preparation of gram-quantities of the Claisen-rearranged product in yields greater than 80% over two simple synthetic steps from the parent resorcinarenes. Microwave assisted solventless rearrangement was also investigated. These novel resorcinarenes have been characterized by crystallographic methods, in addition to the standard spectroscopic techniques.