<p>Crystalline luminescent complexes of europium(III) with hexafluoroacetylacetone, trifluoroacetic acid, and 2,2'-dipyridyl were obtained. The luminescence properties and kinetics of the photodecomposition of these complexes in high-pressure polyethylene were studied. The complex of europium(III) with 2,2'-dipyridyl was shown to have greater photostability. The photoluminescence spectra were shown to result from f–f transitions of the europium(III) ion.</p>

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Luminescence of Europium(III) Hexafluoroacetylacetonate and Trifluoroacetate with 2,2'-dipyridyl

  • I. V. Kalinovskaya,
  • A. G. Mirochnik

摘要

Crystalline luminescent complexes of europium(III) with hexafluoroacetylacetone, trifluoroacetic acid, and 2,2'-dipyridyl were obtained. The luminescence properties and kinetics of the photodecomposition of these complexes in high-pressure polyethylene were studied. The complex of europium(III) with 2,2'-dipyridyl was shown to have greater photostability. The photoluminescence spectra were shown to result from f–f transitions of the europium(III) ion.