For \(m \in \mathbb {N}\) , an m-modular Hadamard matrix is a square matrix of order n with coefficients in \(\{\pm 1\}\) satisfying \( H H^\top \equiv nI_n \bmod m. \) This notion was introduced by Marrero and Butson in the early 1970’s. The case \(m=0\) corresponds to true Hadamard matrices, with rows pairwise orthogonal over \(\mathbb {Z}\) rather than \(\mathbb {Z}/m\mathbb {Z}\) . The m-modular Hadamard conjecture, a consequence of its classical counterpart from 1893, postulates the existence of m-modular Hadamard matrices of any order \(n \equiv 0 \bmod 4\) . It is currently solved for \(m=5, 12, 32\) and their divisors only. In this paper, we make some partial progress toward the open case \(m=64\) , by constructing 64-modular Hadamard matrices of all orders \(n=4\ell \) such that \(\ell \equiv 3 \bmod 16\) or \(\ell \equiv 7 \bmod 32\) . This includes \(n=668\) and 716, the smallest two of the three open cases \(n \le 1000\) in Hadamard’s conjecture proper, leaving \(n=892\) as the smallest open case in the 64-modular version. Our solutions rest on the construction of relevant families of 64-modular Golay quadruples and the Goethals–Seidel array.