Unraveling catalyst-substrate interactions and active sites in carbon supported cobalt sulfide for oxygen evolution reaction
摘要
The exploration of suitable non-precious earth-abundant materials with sufficient active sites and their interaction with a suitable conducting support is very important for efficient water-splitting reactions to generate clean hydrogen fuel. The present study reports the in-situ growth of carbon supported cobalt sulfide (CoS) micro-structured crystals over graphite and copper sheets using a simple brush coated one-step calcinations technique and their electro-catalytic behavior towards oxygen evolution reaction (OER). Carbon supported powder CoS material was also synthesized under identical conditions in order to compare the performance with the material synthesized by in-situ technique. The electrochemical analysis demonstrates that the material grown in-situ over graphite/copper electrodes possesses better catalytic activities than the powder sample. The observed over-potential of the binder free self-supported film electrode for the oxygen evolution reaction (OER) was 270 mV compared to 413 mV for the powder sample to achieve the current density of 10 mA cm−2 in 1 M KOH solution. The synthesized carbon supported CoS materials were further characterized using various spectroscopic techniques, such as, XRD, FE-SEM, EDX and XPS. The long-term durability test of the carbon supported CoS/Gr material was conducted in alkaline medium to confirm its possible uses as a promising electrode material for the oxygen evolution reaction. The long-term stability over 16 h of the carbon supported CoS/Gr material was explained in terms of strong interaction between the active material and the conducting support.
Graphical abstractA study of interaction between binders free self supported CoS films and the conducting graphite sheet for electrochemical oxygen evolution reaction