<p>The influence of the content and ratio of MgO and CaO sintering additives on the optical properties of YAG:Cr<sup>3+</sup> and YAG:Cr<sup>4+</sup> ceramic materials was investigated. All samples showed high transparency at 1100 nm (more than 80%). However, in the approx. 340 nm region, the light transmittance values of the samples decreased with increasing amounts of Ca<sup>2+</sup> or Mg<sup>2+</sup> ions. The most intense absorption in the range of 750 – 1100 nm after annealing in air was observed in the samples containing the highest value of sintering additives. The absorption of Cr<sup>4+</sup> cations increased with the increase of Ca/Mg content. The optimum CaO content among the investigated samples was 0.12 wt.%. Above this value, additional absorption was observed due to the formation of microdefects. The data obtained by scanning electron microscopy showed that the ceramic samples had a granular structure with grain size ranging from 1 to 10 μm. There were no significant differences in the microstructure depending on the content and type of sintering additives.</p>

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Influence of the MgO/CaO Sintering Additive Ratio on the Optical Properties of YAG:Cr Ceramics

  • A. A. Kravtsov,
  • V. E. Suprunchuk,
  • V. A. Tarala,
  • F. F. Malyavin,
  • E. V. Medyanik,
  • L. V. Tarala,
  • D. S. Vakalov,
  • V. A. Lapin,
  • E. A. Brazhko

摘要

The influence of the content and ratio of MgO and CaO sintering additives on the optical properties of YAG:Cr3+ and YAG:Cr4+ ceramic materials was investigated. All samples showed high transparency at 1100 nm (more than 80%). However, in the approx. 340 nm region, the light transmittance values of the samples decreased with increasing amounts of Ca2+ or Mg2+ ions. The most intense absorption in the range of 750 – 1100 nm after annealing in air was observed in the samples containing the highest value of sintering additives. The absorption of Cr4+ cations increased with the increase of Ca/Mg content. The optimum CaO content among the investigated samples was 0.12 wt.%. Above this value, additional absorption was observed due to the formation of microdefects. The data obtained by scanning electron microscopy showed that the ceramic samples had a granular structure with grain size ranging from 1 to 10 μm. There were no significant differences in the microstructure depending on the content and type of sintering additives.