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Technological Methods for Increasing the Fluorine Content in SrO–Al2O3–P2O3–SiO2–F Glass for Glass-Ionomer Cement

  • A. A. Romanenko,
  • V. I. Savinkov,
  • E. M. Zinina,
  • A. A. Buzov,
  • V. P. Shuev,
  • V. N. Sigaev

摘要

The influence of the technological glass-melting parameters of the selected composition in the SrO–Al2O3–P2O3–SiO2–F system on the value of the refractive index and the amount of fluorine remaining in the glass structure post-melting was investigated. The lowering of the melting temperature combined with tableting of the charge [batch] increases fluorine absorption in the glass up to 17 wt.% at the same time, and the value of the refractive index reduction to nD = 1.49. It was experimentally established that in the multicomponent glass selected for glass-ionomer cements with two glass-forming oxides (SiO2 and P2O2) and a high Al2O3 content, each wt.% of fluorine reduces the refractive index by about 3.5 × 10 –4 units.