Geopolymer Crusts from Waste Marble Powder for Sand Dune Stabilization in Arid Climates: A Multi-Performance Assessment
摘要
Wind-driven sand dune migration in arid deserts poses a significant environmental and socio-economic challenge, accelerating desertification, land degradation, and threats to infrastructure and livelihoods. This study investigates a sustainable sand dune fixation (SDF) technique by valorizing industrial waste marble powder (MP), generated at over 6 million metric tons annually in Rajasthan, India, into geopolymer-stabilized sand crusts using MP from local dump yards and desert sand (OS) from Osian dunes, thereby advancing circular economy principles and waste management practices. Performance of the developed geopolymer crust was assessed comprehensively through mechanical, microstructural, and environmental tests. Unconfined compressive strength (UCS) tests demonstrated rapid strength gains (within 24 h), reaching 4.43 MPa, facilitating quick field deployment. The later strength gained up to 9.7 MPa for 14-day curing condition. Wind tunnel tests on scaled sloped dune models indicated that a 25% MP-75% OS formulation exhibited superior erosion resistance (zero soil mass loss at 9.1 m/s), penetration resistance (> 343 kPa), and crust thickness (6–12 mm). Field emission scanning electron microscopy with energy-dispersive X-ray spectroscopy (FESEM-EDS) confirmed dense calcium-alumino-silicate-hydrate (CASH) gels with low porosity, enhancing mechanical durability of the crust material. Leaching assessments via toxicity characteristic leaching procedure (TCLP) and synthetic precipitation leaching procedure (SPLP) verified environmental safety, with no hazardous heavy metal release. These results establish MP-OS geopolymers as a cost-effective, scalable, and eco-friendly SDF solution, supporting Sustainable Development Goal 15 in combating land degradation via waste reuse. Field-scale trials under diverse climatic conditions are recommended to confirm long-term effectiveness and scalability.