Impacts of fireworks on urban air quality during Spring Festivals of 2022–2024 in Shandong Province, China
摘要
This study analyzed the impact of firework discharge on urban air quality during the Spring Festivals of 2022–2024 in Shandong Province, China, with a focus on PM₂.₅ concentration variations and their sources. Based on the monitoring data of conventional pollutants (SO₂, NO₂, PM₂.₅, PM10, CO, and O3) and chemical components of PM₂.₅ across 16 cities in Shandong Province, combined with meteorological conditions, the contribution of fireworks to PM₂.₅ and its source apportionment were evaluated, using the CO ratio method and positive matrix factorization (PMF) model. The results showed that PM₂.₅ concentrations surged significantly during the Spring Festival period in 2024, peaking at 423 µg/m3, which was 11.1 times and 1.2 times higher than those in 2022 and 2023, with fireworks contributing 49% to the daily average of PM₂.₅. During the concentrated discharge periods of fireworks (FCDP) in 2024, the proportions of NO3− and NH4+ in PM2.5 decreased by 21.5% and 10.7%, respectively, while those of tracer components of fireworks, such as K+, Cl−, SO42−, and Mg2+, increased by 17.2%, 7.7%, 5.9%, and 1.7%, respectively, showing the impact of fireworks. PMF source apportionment revealed that fireworks accounted for 59% of PM₂.₅ during the FCDP, rather than secondary sources (35%) and motor vehicles (21%) during the benchmark period (BP). The suggestions to the government were proposed, including strengthening policy implementation, optimizing discharge controls, and promoting public awareness of eco-friendly celebrations to reduce reliance on traditional fireworks.