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<p>Liquid crystal elastomers (LCEs) marry the large deformation response of a cross-linked polymer network with the nematic order of liquid crystals pendent to the network. Of particular interest is the actuation of LCE sheets where the nematic order, modeled by a unit vector called the director, is specified heterogeneously in the plane of the sheet. Heating such a sheet leads to a large spontaneous deformation, coupled to the director design through a metric constraint that is now well-established by the literature. Here we go beyond the metric constraint and identify the full plate theory that underlies this phenomenon. Starting from a widely used bulk model for LCEs, we derive a plate theory for the pure bending deformations of patterned LCE sheets in the limit that the sheet thickness tends to zero using the framework of <InlineEquation ID="IEq1"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="10659_2025_10127_Article_IEq1.gif" Format="GIF" Height="14" Rendition="HTML" Resolution="72" Type="Linedraw" Width="12" /> </InlineMediaObject> <EquationSource Format="MATHML"><math> <mi mathvariant="normal">Γ</mi> </math></EquationSource> <EquationSource Format="TEX">$\Gamma $</EquationSource> </InlineEquation>-convergence. Specifically, after dividing the bulk energy by the cube of the thickness to set a bending scale, we show that all limiting midplane deformations with bounded energy at this scale satisfy the aforementioned metric constraint. We then identify the energy of our plate theory as an ansatz-free lower bound of the limit of the scaled bulk energy, and construct a recovery sequence that achieves this plate energy for all smooth enough midplane deformations. We conclude by applying our plate theory to a variety of examples.</p>

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Plate Theory for Metric-Constrained Actuation of Liquid Crystal Elastomer Sheets

  • 期刊论文

  • 出版模式：

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  • 发表日期：

    2025年3月26日

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  • Lucas Bouck,
  • David Padilla-Garza,
  • Paul Plucinsky

摘要

Liquid crystal elastomers (LCEs) marry the large deformation response of a cross-linked polymer network with the nematic order of liquid crystals pendent to the network. Of particular interest is the actuation of LCE sheets where the nematic order, modeled by a unit vector called the director, is specified heterogeneously in the plane of the sheet. Heating such a sheet leads to a large spontaneous deformation, coupled to the director design through a metric constraint that is now well-established by the literature. Here we go beyond the metric constraint and identify the full plate theory that underlies this phenomenon. Starting from a widely used bulk model for LCEs, we derive a plate theory for the pure bending deformations of patterned LCE sheets in the limit that the sheet thickness tends to zero using the framework of Γ $\Gamma $ -convergence. Specifically, after dividing the bulk energy by the cube of the thickness to set a bending scale, we show that all limiting midplane deformations with bounded energy at this scale satisfy the aforementioned metric constraint. We then identify the energy of our plate theory as an ansatz-free lower bound of the limit of the scaled bulk energy, and construct a recovery sequence that achieves this plate energy for all smooth enough midplane deformations. We conclude by applying our plate theory to a variety of examples.