Sediment–water exchange and risk assessment of pesticidal persistent organic pollutants in Bharathappuzha and Periyar Riverine region along the Arabian Sea

Considering the extensive agricultural practices along the perennial rivers, viz. Periyar and Bharathappuzha of Kerala in the southwest coast of India, the first comprehensive surveillance of new and legacy organochlorine pesticides (OCPs) in surface sediment was conducted. Further, the sediment–water exchange fluxes have been elucidated. Mean concentrations of total HCH, DDT and endosulfan were 0.84 ng/g, 0.42 ng/g and 0.30 ng/g for Bharathappuzha Riverine sediment (BRS) and 1.08 ng/g, 0.39 ng/g and 0.35 ng/g for Periyar Riverine sediment (PRS). The dominance α-HCH and β-HCH isomers in PRS and BRS reflect the ongoing use of technical HCH in Kerala. The calculated K_SW in both rivers was very low in comparison with other Indian rivers. The average log K′_OC for all the detected OCPs in both the rivers was lower than the predicted log K_OC in equilibrium indicating the higher adherence of OCPs to sediment. Furthermore, fugacity fraction (f_s/f_w) was < 1.0 for all OCPs confirming the net deposition of OCPs into the sediment. Sediment concentrations for each of the OCPs in PRS and BRS did not surpass the threshold effect level and probable effect level as stipulated by the Canadian Council of Ministry of the Environment Guidelines. In addition, all the sites of both rivers had sediment quality guideline quotient (SQGQ) values below 0.1 indicating the absence of significant biological and ecological risks.