It is shown that a normalized complex Hadamard matrix of order 6 having three distinct columns each containing at least one \(-1\) entry, necessarily belongs to the transposed Fourier family, or to the family of 2-circulant complex Hadamard matrices. The proofs rely on solving polynomial systems of equations by Gröbner basis techniques, and make use of a structure theorem concerning regular Hadamard matrices. As a consequence, members of these two families can be easily recognized in practice. In particular, one can identify complex Hadamard matrices appearing in known triplets of pairwise mutually unbiased bases in dimension 6.
